Quand on étudie la déformation des métaux à l’échelle du micromètre, le comportement régulier et…
Learning the constitutive laws of solids could lead to advancements in energy, electronics and many other scientific and engineering applications. For a single-phase, homogeneous material, constitutive relations involving composition are straightforward to characterize. However, learning such laws for materials that are heterogeneous at the nanoscale is substantially more difficult. For example, despite more than two decades of progress, two fundamental questions remain for the currently used battery positive electrode material LiXFePO4. a) what is the extent of elastic coherency domain and plastic deformation at phase boundaries, and b) how does the metastable solid solution expand and contract inside the miscibility gap?
Using X-ray spectro-ptychography and four-dimensional scanning transmission electron microscopy (STEM), the local Li composition and lattice strain in thick LiXFePO4 particles were identified with an image-learning framework employing physical constraint and regularization (Fig. 1). A mostly linear Li concentration-eigenstrain relation across the entire composition range (for X=0.05 – 0.95) was identified, experimentally validating Vegard’s law at the nanoscale.
The lattice strain maps show “hot spots” located around the phase boundaries and inside the phase-separated regions, indicating the existence of dislocations. The analysis of X-ray diffraction peak profiles confirmed the presence of dislocations and allowed determining their Burgers and line vectors.